In the 1861 census there was a George W James, MD, widower living in Wooburn, Bucks and born in Wellesbourne, Warks.

Their marriage from FamilySearch:

First name(s) George
Last name James
Name note -
Marriage year 1855
Marriage date 02 Jan 1855
Marriage place Linchlade
Father's first name(s) George
Father's last name James
Spouse's first name(s) Letitia
Spouse's last name Powys
Spouse's father's first name(s) Thomas
Spouse's father's last name Powys
Residence Linchlade, Buckingham, England
County Buckinghamshire
Country England
Record set England Marriages 1538-1973

Their marriage registration index:

First name(s) GEORGE
Last name JAMES
Marriage quarter 1
Marriage year 1855
Registration month -
MarriageFinder™ GEORGE JAMES married
LETITIA POWYS
District LEIGHTON BUZZARD
District number -
County Bedfordshire
Country England
Volume 3B
Page 495
Record set England & Wales marriages 1837-2008
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